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文章摘要
工业温室气体CO2排放监测技术前期研究
Preliminary Study of Industrial Greenhouse Gas (CO2) Emissions Monitoring Technology
  
DOI:
中文关键词: 工业废气  二氧化碳  红外传感器  非分散红外法  气相色谱法
英文关键词: Industrial waste gas  Carbon dioxide (CO2)  Infrared sensor  Non dispersive infrared analysis method  Gas chromatography
基金项目:国家环境监测总站“工业温室气体排放统计及监测技术前期研究”基金资助项目
作者单位
程钟 常州市环境监测中心 
杨龙誉 常州市环境监测中心 
王军霞 中国环境监测总站 
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中文摘要:
      介绍了国内外二氧化碳(CO2)气体检测方法,选取红外传感器、非分散红外和气相色谱3种方法监测工业燃煤废气中的CO2。试验结果表明,3种方法的精密度和准确度均满足要求;单一燃煤废气中CO2的体积分数范围为6.70%~15.10%,同一排气筒中CO2体积分数5 min的波动范围为0~22.4%;同一排气筒(单一燃煤废气)中CO2和O2的体积分数有一定的关联性,二者之和基本稳定在19%~21%范围;非分散红外法和气相色谱法测定同一样品的相对偏差为0.9%~3.4%;红外传感器适用于有组织排放的现场监测,另2种方法适用于无组织废气和环境空气监测。
英文摘要:
      Domestic and foreign CO2 gas detection methods were introduced and three methods of Infrared sensor, non dispersive infrared analysis and gas chromatography were selected to monitor the concentration of CO2 in industrial coal fired waste gas. According to the experimental results, the precision and accuracy of the three methods all met the requirements. In the exhaust gas containing coal fired waste gas only, the range of volume fraction of CO2 was from 6.70% to 15.10%. In the same exhaust pipe, the fluctuation range of volume fraction of CO2 within 5 minutes was from 0 to 22.4%. In the same exhaust pipe(exhaust gas containing coal fired waste gas only), the volume fraction of CO2 and O2 have some relevance, their sum was basically stable in the range from 19% to 21%. The relative deviation of non dispersive infrared analysis and gas chromatography in testing the same sample ranged from 0.9% to 3.4%. Infrared sensor is suitable for on site monitoring of organized emissions and the other two methods are applicable to unorganized emissions and ambient air monitoring.
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