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高分辨电感耦合等离子体质谱法测定地下水中稀土元素 |
Determination of Rare Earth Elements in Groundwater by High Resolution Inductively Coupled Plasma Mass Spectrometry |
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DOI: |
中文关键词: 稀土元素 高分辨电感耦合等离子体质谱法 地下水 |
英文关键词: Rare earth elements High resolution inductively coupled plasma mass spectrometry (HR ICP MS) Groundwater |
基金项目:国家自然科学基金资助项目(41302209) |
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摘要点击次数: 1907 |
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中文摘要: |
采用高分辨电感耦合等离子体质谱法测定地下水中14种稀土元素,并选择Rh作内标,可消除测定中的质谱干扰和非质谱干扰,使方法在0 μg/L~100 μg/L范围内线性良好。方法检出限为0.002 μg/L~0.005 μg/L,实际水样的加标回收率为80.0%~117%,RSD为2.1%~3.8%。 |
英文摘要: |
14 rare earth elements were detected by high resolution inductively coupled plasma mass spectrometry (HR ICP MS),by choosing Rh as a internal standard,the mass spectral interference and non interference in the detection could be eliminated and the result showed a good linearity in the range of 0 μg/L~100 μg/L.The detection limits of this method were 0.002 μg/L~0.005 μg/L,the recoveries of actual water samples ranged from 80.0% to 117%,and the RSDs were 2.1%~3.8% |
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