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文章摘要
焚烧源二噁英连续采样技术与运行评价
Stack Source of Dioxin Continuous Sampling Technique and Operation Demonstration
  
DOI:
中文关键词: 二噁英  连续采样  高分辨气相色谱-高分辨质谱法  垃圾焚烧  烟道气
英文关键词: Dioxin  Continuous sampling technique  HRGC HRMS  Garbage in cineration  Stack gas
基金项目:国家高科技发展“八六三”计划基金资助项目(2011AA060601)
作者单位
倪余文 中国科学院大连化学物理研究所 
綦懿 大连泰达环保有限公司 
宋逍 大连泰达环保有限公司 
袁和平 中国科学院大连化学物理研究所 
滕曼 中国环境监测总站 
里东 中国科学院大连化学物理研究所 
王振兴 中国科学院大连化学物理研究所 
于达 中国科学院大连化学物理研究所 
陈吉平 中国科学院大连化学物理研究所 
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中文摘要:
      将研发的二噁英连续采样装置与G4型常规烟道气等速采样器同步采样,通过示范运行,考察该连续采样装置的长期采样性能。试验表明,2种采样设备同步采集的样品具有一致性,其二噁英指纹、二噁英浓度和毒性当量相符合。1周的示范运行连续采样试验表明,该连续采样装置中的二噁英捕集材料未发生穿透。1个月的连续采样实测表明,连续采样测定中烟道气排放二噁英毒性当量浓度(以I-TEQ计)为35.0 pg/m3(标况下),采样回收率为71.2%。
英文摘要:
      A comparative study on the synchronous sampling has been conducted by both the imported conventional sampling equipment and the developed automatic continuous sampling equipment in the work.The long term sampling performance has been investigated by the field demonstration running.Similar results have been achieved by both sampling equipments.It has been indicated that the fingerprint,concentrations and total toxic equivalent (TEQ) concentrations of polychlorinated dibenzo p dioxin and dibenzofuran (PCDD/F) congeners were consistent with each other.No penetration through the adsorbing materials has occurred during a week continuous demonstration running.The TEQ concentration of PCDD/Fs in flue gas was measured to be 35.0 pg/m3 by the automatic continuous sampling equipment during a month continuous demonstration running with 71.2% of the sampling recovery rate.
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