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文章摘要
高效液相色谱法测定稻田中氰氟草酯
Determination of Cyhalofop butyl in Paddy Field Environment by HPLC
  
DOI:
中文关键词: 氰氟草酯  消解动态  高效液相色谱法  水稻  土壤  水质
英文关键词: Cyhalofop butyl  Decline study  HPLC  Paddy  Soils  Water quality
基金项目:农业部农药残留基金资助项目(NC2010H431)
作者单位
魏凤 湖南省环境监测中心站湖南农业大学资源环境学院 
杨仁斌 湖南农业大学资源环境学院 
蒋波 湘乡市环境保护局 
毕军平 湖南省环境监测中心站 
欧阳文森 湖南农业大学生物科学技术学院 
聂红英 湖南农业大学生物科学技术学院 
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中文摘要:
      分别对长沙、杭州、长春3处试验田实施氰氟草酯10%水乳剂在稻田环境中的消解动态与最终残留量试验,样品前处理后用高效液相色谱法测定。该方法在5.00 μg/L~5 000 μg/L范围内线性良好,稻田水方法检出限为0.01 mg/L,土壤、植株、稻米和稻壳检出限为0.05 mg/kg~0.07 mg/kg,加标回收率为78.4%~109%,5次试验结果的RSD为1.6%~7.0%。氰氟草酯10%水乳剂在田水、土壤及水稻植株中的半衰期t1/2<30 d,属于易消解农药。农药推荐使用剂量下(1 050 g/hm2),3处试验田收获的稻米最终残留量均为未检出。
英文摘要:
      The dyamic degradation and final residue of 10% water emulsion cyhalofop butyl in three experimental fields in Changsha, Hangzhou, Changchun were investigated, and the samples were detected by high performance liquid chromatography (HPLC) after pretreatment. The results showed that the method had a favorable linear ranged from 5.00 μg/L to 5 000 μg/L, and the detection limits of cyhalofop butyl were 0.01 mg/L in paddy field water, and ranged from 0.05 mg/L to 0.07 mg/kg in soil, plant, rice, and rice hull. The recovery rate ranged from 78.4% to 109%, and RSD ranged from 1.6% to 7.0%(n=5). The half live (t1/2) of cyhalofop butyl(10% Ew) in soil, paddy field water, plant were <30 d, indicating that this herbicide was of easy degradation. The final residues of cyhalofop butyl were not detected in the rice of the three experimental fields under the recommended dosage (1 050 g/hm2).
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