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| 固相萃取-LC-MS/MS测定土壤中多溴联苯醚 |
| Determination of Polybrominated Diphenylethers in Soil by Solid Phase Extraction Liquid Chromatography Tandem Mass Spectrometry |
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| DOI： |
| 中文关键词: 多溴联苯醚 快速溶剂萃取 固相萃取 液相色谱串联质谱法 土壤 |
| 英文关键词: PBDEs Accelerated solvent extraction Solid phase extraction LC MS/MS Soils |
| 基金项目:浙江省基础公益研究计划基金资助项目 （LGG21B070001）；台州市科技计划基金资助项目（1902ky82，1901gy16） |
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| 中文摘要: |
| 采用快速溶剂萃取-固相萃取-液相色谱串联质谱法（LC-MS/MS）测定土壤中8种多溴联苯醚类（PBDEs）化合物，通过优化试验条件，使方法在100 μg/L～1 000 μg/L范围内线性良好，方法检出限为085 μg/kg～125 μg/kg。不同土壤样品的8种多溴联苯醚回收率为68.6%～127%，4次测定结果的RSD为4.8%～27.6%。将该方法用于测定电子废物拆解点周边的土壤样品，结果BDE-209测定值为未检出～168 μg/kg，BDE-183为未检出～560 μg/kg，其余6种BDEs均为未检出。 |
| 英文摘要: |
| Eight kinds of polybrominated diphenyl ethers (PBDEs) in soil were determined by liquid chromatography mass spectrometry(LC MS/MS) with accelerated solvent extraction(ASE) and solid phase extraction(SPE). The linear range of the method was 10.0 μg/L~1 000 μg/L under optimized experimental conditions. The method detection limits were 0.85 μg/kg~1.25 μg/kg . The recoveries of eight kinds of PBDEs in different soil samples were 68.6%~127%, the relative standard deviations (RSD) were 4.8%~27.6%(n=4). The method was applied to the soil samples from around the electronic waste disassembling site. The measurement results of BDE 209 were from undetected to 16.8 μg/kg, BDE 183 were from undetected to 5.60 μg/kg, and other BDES were all undetected. |
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